Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes
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Peer Reviewed
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Author (aut): Dickie, Diane A.
Author (aut): Jalali, Hanifa
Author (aut): Samant, Rahul G.
Author (aut): Jennings, Michael C.
Author (aut): Clyburne, Jason A. C.
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| Abstract |
Abstract
2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized. [ABSTRACT FROM AUTHOR]
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Volume 82, Issue 9
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DOI
10.1139/v04-110
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ISSN
0008-4042
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| Use and Reproduction |
Use and Reproduction
©2004. NRC Research Press. Canadian Society for Chemistry.
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Rights Statement
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| Keywords |
Keywords
Schiff bases
N,O ligands
aluminum
m-terphenyl
X-ray crystallography
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