Clyburne, Jason A. C.

Person Preferred Name
Jason A. C. Clyburne

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Default image for the object m-Terphenyl thiols: rigid and bulky molecules for the formation of bioactive self-assembled monolayers on gold, object is lacking a thumbnail image
m-Terphenyl thiols: rigid and bulky molecules for the formation of bioactive self-assembled monolayers on gold
Content type
Digital Document
Abstract
The m-terphenyl 4-mercaptomethyl-2,6-diphenylbenzoic acid (3), was prepared and shown to form ω-carboxyl terminated self-assembled monolayers (SAMs) on gold with high surface pKa (10.1 ± 0.2) and low density favourable for the binding of biological macromolecules.
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Default image for the object Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes, object is lacking a thumbnail image
Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes
Content type
Digital Document
Abstract
2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized. [ABSTRACT FROM AUTHOR]
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