Jennings, Michael C.

Person Preferred Name
Michael C. Jennings

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Default image for the object Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes, object is lacking a thumbnail image
Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes
Content type
Digital Document
Abstract
2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized. [ABSTRACT FROM AUTHOR]
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