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Level crossing resonance due to chlorine nuclei in a free radical

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Ji, F., Percival, P. W., Brodovitch, J.-C., Addison-Jones, B., & Wlodek, S. (1994). Level crossing resonance due to chlorine nuclei in a free radical. Hyperfine Interactions, 87, 853-858. https://doi.org/10.1007/BF02068474

Description

Details
Author(s)

Ji, Feng
Percival, Paul W.
Brodovitch, Jean-Claude
Addison-Jones, Brenda
Wlodek, Stanislaw

Title

Level crossing resonance due to chlorine nuclei in a free radical

Publication Type

article

Date issued

1994

Journal/Book/Host Title

Hyperfine Interactions

Volume

87

Start Page

853

End Page

858

Abstract

Muonium adds to allyl chloride, CH2=CHCH2Cl, to form two radicals: MuCH2CHCH2Cl (main product) and CH2CHMuCH2Cl (minor product). Both radicals were fully characterized byμSR andμLCR. In the main product, the LCR lines due to the35Cl and37Cl nuclei were observed. Also, the temperature dependence of various hyperfine coupling constants (hfc) indicates that both Mu and Cl eclipse the unpaired electronp 2-orbital in the minimum energy conformation. For the fragment-CH2Cl, the presence of Mu in theβ′-position is found to affect significantly the hfc of Cl in theβ-position; an internal rotational barrier of 12 kJ mol−1 was estimated using a simpleV 2 torsional potential.

DOI

10.1007/BF02068474

ISSN

0304-3843

Publication note

Final article published

Author Keywords

Minimum Energy
Chloride
Thin Film
Free Radical
Chlorine

Language

English

Publisher

Springer

Peer reviewed?

Peer reviewed

Use rights

http://rightsstatements.org/vocab/InC-EDU/1.0/
©1994. Hyperfine Interactions. Springer.