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Detection of an α-Muonium-substituted methyl radical

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Addison-Jones, B., Percival, P. W., Brodovitch, J.-C., Ji, F., Sharma, D., & Wlodek, S. (1994). Detection of an α-Muonium-substituted methyl radical. Hyperfine Interactions, 87, 847-851. https://doi.org/10.1007/BF02068473

Description

Details
Author(s)

Addison-Jones, Brenda
Percival, Paul W.
Brodovitch, Jean-Claude
Ji, Feng
Sharma, Dev
Wlodek, Stanislaw

Title

Detection of an α-Muonium-substituted methyl radical

Publication Type

article

Date issued

1994

Journal/Book/Host Title

Hyperfine Interactions

Volume

87

Start Page

847

End Page

851

Abstract

Reported here is the first observation of anα-Muonium-substituted methyl radical. The key to the success of this experiment was the use of a more stable precursor, trimethylsilyldiazomethane, in lieu of the prototypical diazomethane. The radical, CHMuSi(CH3)3 was observed by TF-μSR, with Aμ=187.6(2) MHz. This result is compared to literature values for the proton analogue and the isotope effect is discussed.

DOI

10.1007/BF02068473

ISSN

0304-3843

Publication note

Final article published

Author Keywords

Stable Precursor
Methyl
Thin Film
Isotope Effect
Diazomethane

Language

English

Publisher

Springer

Peer reviewed?

Peer reviewed

Use rights

http://rightsstatements.org/vocab/InC-EDU/1.0/
©1994. Hyperfine Interactions. Springer.